Search results for " resolve"
showing 10 items of 75 documents
Variable-charge method applied to study coupled grain boundary migration in the presence of oxygen
2009
International audience; One of the important differences between simulation and experiments in grain boundary (GB)-dominated metallic structures is the lack of impurities such as oxygen in computational samples. A modified variable-charge method [Elsener A, Politano O, Derlet PM, Van Swygenhoven H. Modell Simul Mater Sci Eng 2008;16:025006] based on the Streitz and Mintmire approach [Streitz FH, Mintmire JW. Phys Rev B 1994;50:11996] is used to study coupled GB motion in an Al bicrystal with a [1 1 2] symmetrical tilt GB in the presence of substitutional O, and compared with the stick–slip process identified by Cahn and Mishin [Cahn JW, Mishin Y, Suzuki A. Acta Mater 2006;54:4953]. It is found…
Development of branching brittle and ductile shear zones: A numerical study
2017
Continental collision zones are usually associated with large-scale strike-slip shear zones. In most cases these shear zones are complex and consist of multiple strands, varying in width, length, and total displacement. Here we present 2-D numerical models to simulate the formation of such shear zones at different depth levels within the crust, under either brittle (frictional/plastic) or ductile conditions. Localization of shear zones is initiated by a material contrast (heterogeneity) of the material parameters. We systematically test the rate of strain-weakening in brittle and in ductile regimes to understand its influence on the development of shear zone networks. Our simulations sugges…
Femtosecond structural dynamics drives the trans/cis isomerization in photoactive yellow protein
2016
Many biological processes depend on detecting and responding to light. The response is often mediated by a structural change in a protein that begins when absorption of a photon causes isomerization of a chromophore bound to the protein. Pande et al. used x-ray pulses emitted by a free electron laser source to conduct time-resolved serial femtosecond crystallography in the time range of 100 fs to 3 ms. This allowed for the real-time tracking of the trans-cis isomerization of the chromophore in photoactive yellow protein and the associated structural changes in the protein.Science, this issue p. 725A variety of organisms have evolved mechanisms to detect and respond to light, in which the re…
State transition identification in multivariate time series (STIMTS) applied to rotational jump trajectories from single molecules
2018
Time resolved data from single molecule experiments often suffer from contamination with noise due to a low signal level. Identifying a proper model to describe the data thus requires an approach with sufficient model parameters without misinterpreting the noise as relevant data. Here, we report on a generalized data evaluation process to extract states with piecewise constant signal level from simultaneously recorded multivariate data, typical for multichannel single molecule experiments. The method employs the minimum description length principle to avoid overfitting the data by using an objective function, which is based on a tradeoff between fitting accuracy and model complexity. We val…
A Single-sensor High-resolution Panoramic Optical Mapping Configuration for Simultaneous Non-overlapped Complete Atrial and Ventricular Parametric Im…
2017
Nowadays optical mapping (OM) is the primary method for imaging electrophysiologically relevant parameters from the outer surface of Langendorff-perfused hearts. This technique has become essential for comprehensively understanding mechanisms of cardiac propagation during physiological activation, arrhythmia, and therapeutic antiarrhythmic interventions in translational hearts. Panoramic whole heart optical mapping systems, using either multiple cameras, plane mirrors or a combination of both, have been developed to overcome intrinsic visualization limitations to traditional single-sensor designs. However current panoramic OM systems are financially challenging for physiology and engineerin…
Reflexiones a propósito de la protección de datos en el escenario global digital: El derecho de daños en la litigiosidad internacional
2021
La circulación internacional de datos personales constituye un sector pujante en la esfera socio-económica. En tales condiciones, ante la existencia de un tratamiento ilícito de aquellos, el agraviado está legitimado para exigir una indemnización por los daños y perjuicios que se hubieran podido originar en el marco transfronterizo. Tal situación plantea dos cuestiones fundamentales: por un lado, determinar el órgano jurisdiccional competente para conocer de un eventual litigio, y, por otro, precisar la Ley aplicable para resolver la controversia suscitada. En la presente investigación cabe destacar las significativas novedades que introduce el Reglamento (UE) 2016/679, de 27 de abril de 20…
La constitución del parlamento en caso de presuntas irregularidades electorales: Comentario a la stedh de 10 de julio de 2020 : Caso mugemangango c. …
2021
The ECHR analyzes, through this judgment, a claim based on the violation of the rights to free elections and to an effective remedy, the origin of which is found in a series of alleged electoral irregularities. The national body that had to resolve this issue was not impartial, and the complaint procedure lacked adequate and sufficient guarantees
Supramolecular Aggregates in Vacuum: Positively Mono-Charged Sodium Alkanesulfonate Clusters
2010
The formation and structural features of positively mono-charged aggregates of sodium bis(2-ethylhexyl) sulfosuccinate (AOT) and sodium methane—(MetS), butane—(ButS) and octane—(OctS) sulfonate molecules in the gas phase have been investigated by electrospray ionization mass spectrometry, energy-resolved mass spectrometry and density functional theory (DFT) calculations. The experimental results show that the center-of-mass collision energy required to dissociate 50% of these mono-charged aggregates scantly depends on the length of the alkyl chain as well as on the aggregation number. This, together with the large predominance of mono-charged species in the mass spectra, was rationalized i…
Three-Dimensional Calibration for Routine Analyses of Bromide and Nitrate Ions as Indicators of Groundwater Quality in Coastal Territories
2019
Nitrate and bromide ions are generally considered indicators of anthropogenic pollution and seawater intrusion, respectively, in the groundwater of coastal territories. The analysis of these species is generally carried out with routine chromatographic analyses which generally afford partially merged or poorly resolved peaks. In the present paper a simple method for the correct evaluation of their concentration in water is reported. This method does not imply utilization of other instruments or technologies, only the mathematical elaboration of the data obtained from routine analysis of standard solutions containing the two species. Standard binary solutions of nitrate and bromide ions at d…
Time-resolved luminescence and induced absorption in PbWO4
1997
Abstract Luminescence and short-lived induced absorption are studied for two undoped PbWO4 crystals. Luminescence decay at LNT is delayed relative to irradiation pulse. The delay observed is either due to reabsorption of luminescence or due to creation of luminescence center excited states via energy or/and charge transfer after irradiation pulse. Short-lived absorption is observed within 1.1–3.6 eV spectral region at LNT as well as at RT. It is proposed that the short-lived absorption band peaking at ~ 3.5 eV is intrinsic.